CHM114: Exam #3 CHM 114 Exam #3 Practice Exam (Chapters 9.1-9.4, 9.6, 10, 11.1-11.6, 13.1-13.5) Instructor: O. Graudejus Points: 100 Print Name Sign Name Student I.D. # 1. You are responsible for the information on this page. Please read it carefully. 2. If you enter your ASU ID incorrectly on the scantron, a 3 point penalty will be assessed. 3. Code your name and 10 digit affiliate identification number on the separate scantron answer sheet. Use only a #2 pencil 4. Do all calculations on the exam pages. Do not make any unnecessary marks on the answer sheet. 5. This exam consists of 25 multiple choice questions worth 4 points each and a periodic table. Make sure you have them all. 6. Choose the best answer to each of the questions and answer it on the computer-graded answer sheet. Read all responses before making a selection. 7. Read the directions carefully for each problem. 8. Avoid even casual glances at other students’ exams. 9. Stop writing and hand in your scantron answer sheet and your test promptly when instructed. LATE EXAMS MAY HAVE POINTS DEDUCTED. 10. You will have 50 minutes to complete the exam. 11. If you leave early, please do so quietly. 12. Work the easiest problems first. 13. A periodic table is attached as the last page to this exam. 14. Answers will be posted online this afternoon. Potentially useful information: K = ºC + 273.15 PV=nRT R=8.314 J·K-1·mol-1 DE = q + w 760 torr = 1 atm = 101325 Pa = 1.013 bar Avogadro’s Number = 6.022 × 1023 particles/mole q = (Sp. Heat) × m × DT (Specific Heatwater = 4.184 J/g°C) 1 2 2 3 2 ( is a constant) KE mv KE RT R = = M RT u 3 = \ -2- CHM 114: Exam #3 1) Of the following molecules, only __________ is polar. A) CCl4 B) BCl3 C) NCl3 D) BeCl2 E) Cl2 2) The molecular geometry of the CHF3 molecule is __________, and the molecule is __________. A) trigonal pyramidal, polar B) tetrahedral, nonpolar C) seesaw, nonpolar D) tetrahedral, polar E) seesaw, polar 3) The electron-domain geometry of __________ is tetrahedral. A) 4 CBr B) 3 PH C) 2 2 CCl Br D) 4 XeF E) all of the above except 4 XeF 4) Of the following substances, only __________ has London dispersion forces as its only intermolecular force. A) H2O B) CCl4 C) HF D) CH3COOH E) PH3 5) The principal reason for the extremely low solubility of NaCl in benzene (C6H6) is the __________. A) strong solvent-solvent interactions B) hydrogen bonding in C6H6 C) strength of the covalent bond in NaCl D) weak solvation (interaction) of Na+ and Cl- by C6H6 E) increased disorder due to mixing of solute and solvent -3- CHM 114: Exam #3 6) There are __________  and __________  bonds in the H −C º C−H molecule. A) 3 and 2 B) 3 and 4 C) 4 and 3 D) 2 and 3 E) 5 and 0 7) A sample of a gas (5.0 mol) at 1.0 atm is expanded at constant temperature from 10 L to 15 L. The final pressure is __________ atm. A) 1.5 B) 7.5 C) 0.67 D) 3.3 E) 15 8) A mixture of He and Ne at a total pressure of 0.95 atm is found to contain 0.32 mol of He and 0.56 mol of Ne. The partial pressure of Ne is __________ atm. A) 1.7 B) 1.5 C) 0.60 D) 0.35 E) 1.0 9) Automobile air bags use the decomposition of sodium azide as their source of gas for rapid inflation: 3 2 2NaN (s)®2Na (s) + 3N (g) . What mass (g) of 3 NaN is required to provide 40.0 L of 2 N at 25.0 °C and 763 torr? A) 1.64 B) 1.09 C) 160 D) 71.1  10) The reaction of 50 mL of 2 Cl gas with 50 mL of 4 CH gas via the equation: 2 4 3 Cl (g) + CH (g)®HCl (g) + CH Cl (g) will produce a total of __________ mL of products if pressure and temperature are kept constant. A) 100 B) 50 C) 200 D) 150 E) 250 -4- CHM 114: Exam #3 11) The density of 2 N O at 1.53 atm and 45.2 °C is __________ g/L. A) 18.2 B) 1.76 C) 0.388 D) 9.99 E) 2.58 12) A gas at a pressure of 325 torr exerts a force of __________ N on an area of 2 5.5 m . A)1.8×103 B) 59 C) 5 2.4×10 D) 0.018 E) 2.4 13) According to kinetic-molecular theory, in which of the following gases will the root-mean-square speed of the molecules be the highest at 200 °C? A) HCl B) 2 Cl C) 2 H O D) 6 SF E) None. The molecules of all gases have the same root-mean-square speed at any given temperature. 14) A real gas will behave most like an ideal gas under conditions of __________. A) high temperature and high pressure B) high temperature and low pressure C) low temperature and high pressure D) low temperature and low pressure E) STP 15) Elemental iodine (I2) is a solid at room temperature. What is the major attractive force that exists among different I2 molecules in the solid? A) London dispersion forces B) dipole-dipole rejections C) ionic-dipole interactions D) covalent-ionic interactions E) dipole-dipole attractions -5- CHM 114: Exam #3 16) The heat of fusion of water is 6.01 kJ/mol. The heat capacity of liquid water is 75.3 Jmol-1K-1. The conversion of 50.0 g of ice at 0.00 °C to liquid water at 22.0 °C requires __________ kJ of heat. A) 3.8×102 B) 21.3 C) 17.2 D) 0.469 E) Insufficient data are given. 17) Of the following substances, __________ has the highest boiling point. A) 2 H O B) 2 CO C) 4 CH D) Kr E) SF4 18) Which statements about viscosity are true? (i) Viscosity increases as temperature decreases. (ii) Viscosity increases as molecular weight increases. (iii) Viscosity increases as intermolecular forces increase. A) (i) only B) (ii) and (iii) C) (i) and (iii) D) none E) all 19) Based on molecular mass and dipole moment of the five compounds in the table below, which should have the highest boiling point? A) 3 2 3 CH CH CH B) 3 3 CH OCH C) 3 CH Cl D) 3 CH CHO E) 3 CH CN -6- CHM 114: Exam #3 20) On the phase diagram shown above, the coordinates of point __________ correspond to the critical temperature and pressure. A) A B) B C) C D) D E) E 21) The vapor pressure of pure ethanol at 60 °C is 0.459 atm. Raoult’s Law predicts that a solution prepared by dissolving 10.0 mmol naphthalene (nonvolatile) in 90.0 mmol ethanol will have a vapor pressure of _______ atm. A) 0.498 B) 0.413 C) 0.790 D) 0.367 E) 0.0918 Of the following, a 0.1 M aqueous solution of __________ will have the highest freezing point. A) NaCl B) Al(NO3)3 C) K2CrO4 D) Na2SO4 E) sucrose (a sugar) 23) What is the freezing point (°C) of a solution prepared by dissolving 11.3 g of Ca(NO3)2 (formula weight = 164 g/mol) in 115 g of water? The molal freezing point depression constant for water is 1.86 °C/m. A) -3.34 B) -1.11 C) 3.34 D) 1.11 E) 0.00 -7- CHM 114: Exam #3 24) The phase changes B  C and D  E are not associated with temperature increases because the heat energy is used up to __________. A) break intermolecular bonds B) break intramolecular bonds C) rearrange atoms within molecules D) increase the velocity of molecules E) increase the density of the sample 25) Ammonium nitrate (NH4NO3) dissolves readily in water even though the dissolution is endothermic by 26.4 kJ/mol. The solution process is spontaneous because __________. A) the vapor pressure of the water decreases upon addition of the solute B) the ammonium and the nitrate ion both contain nitrogen C) of the decrease in enthalpy upon addition of the solute D) of the increase in enthalpy upon dissolution of this strong electrolyte E) of the increase in disorder (entropy) upon dissolution of this strong electrolyte    -8- CHM 114: Exam #3

CHM114: Exam #3 CHM 114 Exam #3 Practice Exam (Chapters 9.1-9.4, 9.6, 10, 11.1-11.6, 13.1-13.5) Instructor: O. Graudejus Points: 100 Print Name Sign Name Student I.D. # 1. You are responsible for the information on this page. Please read it carefully. 2. If you enter your ASU ID incorrectly on the scantron, a 3 point penalty will be assessed. 3. Code your name and 10 digit affiliate identification number on the separate scantron answer sheet. Use only a #2 pencil 4. Do all calculations on the exam pages. Do not make any unnecessary marks on the answer sheet. 5. This exam consists of 25 multiple choice questions worth 4 points each and a periodic table. Make sure you have them all. 6. Choose the best answer to each of the questions and answer it on the computer-graded answer sheet. Read all responses before making a selection. 7. Read the directions carefully for each problem. 8. Avoid even casual glances at other students’ exams. 9. Stop writing and hand in your scantron answer sheet and your test promptly when instructed. LATE EXAMS MAY HAVE POINTS DEDUCTED. 10. You will have 50 minutes to complete the exam. 11. If you leave early, please do so quietly. 12. Work the easiest problems first. 13. A periodic table is attached as the last page to this exam. 14. Answers will be posted online this afternoon. Potentially useful information: K = ºC + 273.15 PV=nRT R=8.314 J·K-1·mol-1 DE = q + w 760 torr = 1 atm = 101325 Pa = 1.013 bar Avogadro’s Number = 6.022 × 1023 particles/mole q = (Sp. Heat) × m × DT (Specific Heatwater = 4.184 J/g°C) 1 2 2 3 2 ( is a constant) KE mv KE RT R = = M RT u 3 = \ -2- CHM 114: Exam #3 1) Of the following molecules, only __________ is polar. A) CCl4 B) BCl3 C) NCl3 D) BeCl2 E) Cl2 2) The molecular geometry of the CHF3 molecule is __________, and the molecule is __________. A) trigonal pyramidal, polar B) tetrahedral, nonpolar C) seesaw, nonpolar D) tetrahedral, polar E) seesaw, polar 3) The electron-domain geometry of __________ is tetrahedral. A) 4 CBr B) 3 PH C) 2 2 CCl Br D) 4 XeF E) all of the above except 4 XeF 4) Of the following substances, only __________ has London dispersion forces as its only intermolecular force. A) H2O B) CCl4 C) HF D) CH3COOH E) PH3 5) The principal reason for the extremely low solubility of NaCl in benzene (C6H6) is the __________. A) strong solvent-solvent interactions B) hydrogen bonding in C6H6 C) strength of the covalent bond in NaCl D) weak solvation (interaction) of Na+ and Cl- by C6H6 E) increased disorder due to mixing of solute and solvent -3- CHM 114: Exam #3 6) There are __________  and __________  bonds in the H −C º C−H molecule. A) 3 and 2 B) 3 and 4 C) 4 and 3 D) 2 and 3 E) 5 and 0 7) A sample of a gas (5.0 mol) at 1.0 atm is expanded at constant temperature from 10 L to 15 L. The final pressure is __________ atm. A) 1.5 B) 7.5 C) 0.67 D) 3.3 E) 15 8) A mixture of He and Ne at a total pressure of 0.95 atm is found to contain 0.32 mol of He and 0.56 mol of Ne. The partial pressure of Ne is __________ atm. A) 1.7 B) 1.5 C) 0.60 D) 0.35 E) 1.0 9) Automobile air bags use the decomposition of sodium azide as their source of gas for rapid inflation: 3 2 2NaN (s)®2Na (s) + 3N (g) . What mass (g) of 3 NaN is required to provide 40.0 L of 2 N at 25.0 °C and 763 torr? A) 1.64 B) 1.09 C) 160 D) 71.1  10) The reaction of 50 mL of 2 Cl gas with 50 mL of 4 CH gas via the equation: 2 4 3 Cl (g) + CH (g)®HCl (g) + CH Cl (g) will produce a total of __________ mL of products if pressure and temperature are kept constant. A) 100 B) 50 C) 200 D) 150 E) 250 -4- CHM 114: Exam #3 11) The density of 2 N O at 1.53 atm and 45.2 °C is __________ g/L. A) 18.2 B) 1.76 C) 0.388 D) 9.99 E) 2.58 12) A gas at a pressure of 325 torr exerts a force of __________ N on an area of 2 5.5 m . A)1.8×103 B) 59 C) 5 2.4×10 D) 0.018 E) 2.4 13) According to kinetic-molecular theory, in which of the following gases will the root-mean-square speed of the molecules be the highest at 200 °C? A) HCl B) 2 Cl C) 2 H O D) 6 SF E) None. The molecules of all gases have the same root-mean-square speed at any given temperature. 14) A real gas will behave most like an ideal gas under conditions of __________. A) high temperature and high pressure B) high temperature and low pressure C) low temperature and high pressure D) low temperature and low pressure E) STP 15) Elemental iodine (I2) is a solid at room temperature. What is the major attractive force that exists among different I2 molecules in the solid? A) London dispersion forces B) dipole-dipole rejections C) ionic-dipole interactions D) covalent-ionic interactions E) dipole-dipole attractions -5- CHM 114: Exam #3 16) The heat of fusion of water is 6.01 kJ/mol. The heat capacity of liquid water is 75.3 Jmol-1K-1. The conversion of 50.0 g of ice at 0.00 °C to liquid water at 22.0 °C requires __________ kJ of heat. A) 3.8×102 B) 21.3 C) 17.2 D) 0.469 E) Insufficient data are given. 17) Of the following substances, __________ has the highest boiling point. A) 2 H O B) 2 CO C) 4 CH D) Kr E) SF4 18) Which statements about viscosity are true? (i) Viscosity increases as temperature decreases. (ii) Viscosity increases as molecular weight increases. (iii) Viscosity increases as intermolecular forces increase. A) (i) only B) (ii) and (iii) C) (i) and (iii) D) none E) all 19) Based on molecular mass and dipole moment of the five compounds in the table below, which should have the highest boiling point? A) 3 2 3 CH CH CH B) 3 3 CH OCH C) 3 CH Cl D) 3 CH CHO E) 3 CH CN -6- CHM 114: Exam #3 20) On the phase diagram shown above, the coordinates of point __________ correspond to the critical temperature and pressure. A) A B) B C) C D) D E) E 21) The vapor pressure of pure ethanol at 60 °C is 0.459 atm. Raoult’s Law predicts that a solution prepared by dissolving 10.0 mmol naphthalene (nonvolatile) in 90.0 mmol ethanol will have a vapor pressure of _______ atm. A) 0.498 B) 0.413 C) 0.790 D) 0.367 E) 0.0918 Of the following, a 0.1 M aqueous solution of __________ will have the highest freezing point. A) NaCl B) Al(NO3)3 C) K2CrO4 D) Na2SO4 E) sucrose (a sugar) 23) What is the freezing point (°C) of a solution prepared by dissolving 11.3 g of Ca(NO3)2 (formula weight = 164 g/mol) in 115 g of water? The molal freezing point depression constant for water is 1.86 °C/m. A) -3.34 B) -1.11 C) 3.34 D) 1.11 E) 0.00 -7- CHM 114: Exam #3 24) The phase changes B  C and D  E are not associated with temperature increases because the heat energy is used up to __________. A) break intermolecular bonds B) break intramolecular bonds C) rearrange atoms within molecules D) increase the velocity of molecules E) increase the density of the sample 25) Ammonium nitrate (NH4NO3) dissolves readily in water even though the dissolution is endothermic by 26.4 kJ/mol. The solution process is spontaneous because __________. A) the vapor pressure of the water decreases upon addition of the solute B) the ammonium and the nitrate ion both contain nitrogen C) of the decrease in enthalpy upon addition of the solute D) of the increase in enthalpy upon dissolution of this strong electrolyte E) of the increase in disorder (entropy) upon dissolution of this strong electrolyte    -8- CHM 114: Exam #3

COMP 4440/5440 – Dr. Erdemir Mobile Robotics Project (DUE 12/02/2015) HONOR CODE I pledge my honor that I have neither given nor received aid on this work. Do not sign until after you have completed your assignment. Name: Signature: 1. (Prerequisite) Given the asset package (it is in mytsu under assignments folder) download it, open a new project (don’t double click on the file, it won’t open), go to Assets/Import Package/Custom Package, select the asset package given to you (project.unitypackage). After the import is completed, you will see main scene in the assets folder of your project. Double click on it, and choose “Don’t Save” option if it asks for save. 2. Print this page and attach it to your code and your snapshot of your final scene (5 points) 3. After the class starts, instructor will come next to you and you are supposed to show him your code running (10 points) 4. When you run the code you will see, your robot (red cube that we used in the class) is trying to reach the targets but it can’t due to an obstacle between your robot and the targets. Write a code that makes this robot to avoid from the obstacles and reach the targets. Your code will read the collision and intelligently avoid from other moving robots and fixed obstacles and get the three targets. (50 points) 5. Maximum time is 2 minutes, your robot shall get the targets in 2 minutes (10 points) 6. Your robot shall escape from the blue robot and not collide them. (10 Points) 7. Anything extra (up to 20 points) ? Moving objects, new sensor, Artificial Intelligence or other techniques. 8. YOU CAN NOT USE TRANSLATE FUNCTION. USE ONLY AddRelativeForce FUNCTION IN THE FORWARD DIRECTION AS ALL THE MOBILE ROBOTS WORK.

COMP 4440/5440 – Dr. Erdemir Mobile Robotics Project (DUE 12/02/2015) HONOR CODE I pledge my honor that I have neither given nor received aid on this work. Do not sign until after you have completed your assignment. Name: Signature: 1. (Prerequisite) Given the asset package (it is in mytsu under assignments folder) download it, open a new project (don’t double click on the file, it won’t open), go to Assets/Import Package/Custom Package, select the asset package given to you (project.unitypackage). After the import is completed, you will see main scene in the assets folder of your project. Double click on it, and choose “Don’t Save” option if it asks for save. 2. Print this page and attach it to your code and your snapshot of your final scene (5 points) 3. After the class starts, instructor will come next to you and you are supposed to show him your code running (10 points) 4. When you run the code you will see, your robot (red cube that we used in the class) is trying to reach the targets but it can’t due to an obstacle between your robot and the targets. Write a code that makes this robot to avoid from the obstacles and reach the targets. Your code will read the collision and intelligently avoid from other moving robots and fixed obstacles and get the three targets. (50 points) 5. Maximum time is 2 minutes, your robot shall get the targets in 2 minutes (10 points) 6. Your robot shall escape from the blue robot and not collide them. (10 Points) 7. Anything extra (up to 20 points) ? Moving objects, new sensor, Artificial Intelligence or other techniques. 8. YOU CAN NOT USE TRANSLATE FUNCTION. USE ONLY AddRelativeForce FUNCTION IN THE FORWARD DIRECTION AS ALL THE MOBILE ROBOTS WORK.

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Extra Credit Due: 11:59pm on Thursday, May 15, 2014 You will receive no credit for items you complete after the assignment is due. Grading Policy A Man Running to Catch a Bus A man is running at speed (much less than the speed of light) to catch a bus already at a stop. At , when he is a distance from the door to the bus, the bus starts moving with the positive acceleration . Use a coordinate system with at the door of the stopped bus. Part A What is , the position of the man as a function of time? Answer symbolically in terms of the variables , , and . Hint 1. Which equation should you use for the man’s speed? Because the man’s speed is constant, you may use . ANSWER: Correct Part B What is , the position of the bus as a function of time? Answer symbolically in terms of and . = Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 1 of 57 5/9/2014 8:02 PM Hint 1. Which equation should you use for the bus’s acceleration? Because the bus has constant acceleration, you may use . Recall that . ANSWER: Correct Part C What condition is necessary for the man to catch the bus? Assume he catches it at time . Hint 1. How to approach this problem If the man is to catch the bus, then at some moment in time , the man must arrive at the position of the door of the bus. How would you express this condition mathematically? ANSWER: Correct Part D Inserting the formulas you found for and into the condition , you obtain the following: , or . Intuitively, the man will not catch the bus unless he is running fast enough. In mathematical terms, there is a constraint on the man’s speed so that the equation above gives a solution for that is a real positive number. Find , the minimum value of for which the man will catch the bus. Express the minimum value for the man’s speed in terms of and . = Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 2 of 57 5/9/2014 8:02 PM Hint 1. Consider the discriminant Use the quadratic equation to solve: . What is the discriminant (the part under the radical) of the solution for ? Hint 1. The quadratic formula Recall: If then ANSWER: Hint 2. What is the constraint? To get a real value for , the discriminant must be greater then or equal to zero. This condition yields a constraint that exceed . ANSWER: Correct Part E Assume that the man misses getting aboard when he first meets up with the bus. Does he get a second chance if he continues to run at the constant speed ? = = Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 3 of 57 5/9/2014 8:02 PM Hint 1. What is the general quadratic equation? The general quadratic equation is , where , , and are constants. Depending on the value of the discriminant, , the equation may have two real valued 1. solutions if , 2. one real valued solution if , or 3. two complex valued solutions if . In this case, every real valued solution corresponds to a time at which the man is at the same position as the door of the bus. ANSWER: Correct Adding and Subtracting Vectors Conceptual Question Six vectors (A to F) have the magnitudes and directions indicated in the figure. Part A Which two vectors, when added, will have the largest (positive) x component? Hint 1. Largest x component The two vectors with the largest x components will, when combined, give the resultant with the largest x component. Keep in mind that positive x components are larger than negative x components. No; there is no chance he is going to get aboard. Yes; he will get a second chance Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 4 of 57 5/9/2014 8:02 PM ANSWER: Correct Part B Which two vectors, when added, will have the largest (positive) y component? Hint 1. Largest y component The two vectors with the largest y components will, when combined, give the resultant with the largest y component. Keep in mind that positive y components are larger than negative y components. ANSWER: Correct Part C Which two vectors, when subtracted (i.e., when one vector is subtracted from the other), will have the largest magnitude? Hint 1. Subtracting vectors To subtract two vectors, add a vector with the same magnitude but opposite direction of one of the vectors to the other vector. ANSWER: C and E E and F A and F C and D B and D C and D A and F E and F A and B E and D Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 5 of 57 5/9/2014 8:02 PM Correct Tactics Box 3.1 Determining the Components of a Vector Learning Goal: To practice Tactics Box 3.1 Determining the Components of a Vector. When a vector is decomposed into component vectors and parallel to the coordinate axes, we can describe each component vector with a single number (a scalar) called the component. This tactics box describes how to determine the x component and y component of vector , denoted and . TACTICS BOX 3.1 Determining the components of a vector The absolute value of the x component is the magnitude of the 1. component vector . The sign of is positive if points in the positive x direction; it is negative if points in the negative x direction. 2. 3. The y component is determined similarly. Part A What is the magnitude of the component vector shown in the figure? Express your answer in meters to one significant figure. ANSWER: A and F A and E D and B C and D E and F Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 6 of 57 5/9/2014 8:02 PM Correct Part B What is the sign of the y component of vector shown in the figure? ANSWER: Correct Part C Now, combine the information given in the tactics box above to find the x and y components, and , of vector shown in the figure. Express your answers, separated by a comma, in meters to one significant figure. = 5 positive negative Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 7 of 57 5/9/2014 8:02 PM ANSWER: Correct Conceptual Problem about Projectile Motion Learning Goal: To understand projectile motion by considering horizontal constant velocity motion and vertical constant acceleration motion independently. Projectile motion refers to the motion of unpowered objects (called projectiles) such as balls or stones moving near the surface of the earth under the influence of the earth’s gravity alone. In this analysis we assume that air resistance can be neglected. An object undergoing projectile motion near the surface of the earth obeys the following rules: An object undergoing projectile motion travels horizontally at a constant rate. That is, the x component of its velocity, , is constant. 1. An object undergoing projectile motion moves vertically with a constant downward acceleration whose magnitude, denoted by , is equal to 9.80 near the surface of the earth. Hence, the y component of its velocity, , changes continuously. 2. An object undergoing projectile motion will undergo the horizontal and vertical motions described above from the instant it is launched until the instant it strikes the ground again. Even though the horizontal and vertical motions can be treated independently, they are related by the fact that they occur for exactly the same amount of time, namely the time the projectile is in the air. 3. The figure shows the trajectory (i.e., the path) of a ball undergoing projectile motion over level ground. The time corresponds to the moment just after the ball is launched from position and . Its launch velocity, also called the initial velocity, is . Two other points along the trajectory are indicated in the figure. One is the moment the ball reaches the peak of its trajectory, at time with velocity . Its position at this moment is denoted by or since it is at its maximum height. The other point, at time with velocity , corresponds to the moment just before the ball strikes the ground on the way back down. At this time its position is , also known as ( since it is at its maximum horizontal range. Projectile motion is symmetric about the peak, provided the object lands at the same vertical height from which is was launched, as is the case here. Hence . Part A , = -2,-5 , Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 8 of 57 5/9/2014 8:02 PM How do the speeds , , and (at times ,

Extra Credit Due: 11:59pm on Thursday, May 15, 2014 You will receive no credit for items you complete after the assignment is due. Grading Policy A Man Running to Catch a Bus A man is running at speed (much less than the speed of light) to catch a bus already at a stop. At , when he is a distance from the door to the bus, the bus starts moving with the positive acceleration . Use a coordinate system with at the door of the stopped bus. Part A What is , the position of the man as a function of time? Answer symbolically in terms of the variables , , and . Hint 1. Which equation should you use for the man’s speed? Because the man’s speed is constant, you may use . ANSWER: Correct Part B What is , the position of the bus as a function of time? Answer symbolically in terms of and . = Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 1 of 57 5/9/2014 8:02 PM Hint 1. Which equation should you use for the bus’s acceleration? Because the bus has constant acceleration, you may use . Recall that . ANSWER: Correct Part C What condition is necessary for the man to catch the bus? Assume he catches it at time . Hint 1. How to approach this problem If the man is to catch the bus, then at some moment in time , the man must arrive at the position of the door of the bus. How would you express this condition mathematically? ANSWER: Correct Part D Inserting the formulas you found for and into the condition , you obtain the following: , or . Intuitively, the man will not catch the bus unless he is running fast enough. In mathematical terms, there is a constraint on the man’s speed so that the equation above gives a solution for that is a real positive number. Find , the minimum value of for which the man will catch the bus. Express the minimum value for the man’s speed in terms of and . = Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 2 of 57 5/9/2014 8:02 PM Hint 1. Consider the discriminant Use the quadratic equation to solve: . What is the discriminant (the part under the radical) of the solution for ? Hint 1. The quadratic formula Recall: If then ANSWER: Hint 2. What is the constraint? To get a real value for , the discriminant must be greater then or equal to zero. This condition yields a constraint that exceed . ANSWER: Correct Part E Assume that the man misses getting aboard when he first meets up with the bus. Does he get a second chance if he continues to run at the constant speed ? = = Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 3 of 57 5/9/2014 8:02 PM Hint 1. What is the general quadratic equation? The general quadratic equation is , where , , and are constants. Depending on the value of the discriminant, , the equation may have two real valued 1. solutions if , 2. one real valued solution if , or 3. two complex valued solutions if . In this case, every real valued solution corresponds to a time at which the man is at the same position as the door of the bus. ANSWER: Correct Adding and Subtracting Vectors Conceptual Question Six vectors (A to F) have the magnitudes and directions indicated in the figure. Part A Which two vectors, when added, will have the largest (positive) x component? Hint 1. Largest x component The two vectors with the largest x components will, when combined, give the resultant with the largest x component. Keep in mind that positive x components are larger than negative x components. No; there is no chance he is going to get aboard. Yes; he will get a second chance Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 4 of 57 5/9/2014 8:02 PM ANSWER: Correct Part B Which two vectors, when added, will have the largest (positive) y component? Hint 1. Largest y component The two vectors with the largest y components will, when combined, give the resultant with the largest y component. Keep in mind that positive y components are larger than negative y components. ANSWER: Correct Part C Which two vectors, when subtracted (i.e., when one vector is subtracted from the other), will have the largest magnitude? Hint 1. Subtracting vectors To subtract two vectors, add a vector with the same magnitude but opposite direction of one of the vectors to the other vector. ANSWER: C and E E and F A and F C and D B and D C and D A and F E and F A and B E and D Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 5 of 57 5/9/2014 8:02 PM Correct Tactics Box 3.1 Determining the Components of a Vector Learning Goal: To practice Tactics Box 3.1 Determining the Components of a Vector. When a vector is decomposed into component vectors and parallel to the coordinate axes, we can describe each component vector with a single number (a scalar) called the component. This tactics box describes how to determine the x component and y component of vector , denoted and . TACTICS BOX 3.1 Determining the components of a vector The absolute value of the x component is the magnitude of the 1. component vector . The sign of is positive if points in the positive x direction; it is negative if points in the negative x direction. 2. 3. The y component is determined similarly. Part A What is the magnitude of the component vector shown in the figure? Express your answer in meters to one significant figure. ANSWER: A and F A and E D and B C and D E and F Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 6 of 57 5/9/2014 8:02 PM Correct Part B What is the sign of the y component of vector shown in the figure? ANSWER: Correct Part C Now, combine the information given in the tactics box above to find the x and y components, and , of vector shown in the figure. Express your answers, separated by a comma, in meters to one significant figure. = 5 positive negative Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 7 of 57 5/9/2014 8:02 PM ANSWER: Correct Conceptual Problem about Projectile Motion Learning Goal: To understand projectile motion by considering horizontal constant velocity motion and vertical constant acceleration motion independently. Projectile motion refers to the motion of unpowered objects (called projectiles) such as balls or stones moving near the surface of the earth under the influence of the earth’s gravity alone. In this analysis we assume that air resistance can be neglected. An object undergoing projectile motion near the surface of the earth obeys the following rules: An object undergoing projectile motion travels horizontally at a constant rate. That is, the x component of its velocity, , is constant. 1. An object undergoing projectile motion moves vertically with a constant downward acceleration whose magnitude, denoted by , is equal to 9.80 near the surface of the earth. Hence, the y component of its velocity, , changes continuously. 2. An object undergoing projectile motion will undergo the horizontal and vertical motions described above from the instant it is launched until the instant it strikes the ground again. Even though the horizontal and vertical motions can be treated independently, they are related by the fact that they occur for exactly the same amount of time, namely the time the projectile is in the air. 3. The figure shows the trajectory (i.e., the path) of a ball undergoing projectile motion over level ground. The time corresponds to the moment just after the ball is launched from position and . Its launch velocity, also called the initial velocity, is . Two other points along the trajectory are indicated in the figure. One is the moment the ball reaches the peak of its trajectory, at time with velocity . Its position at this moment is denoted by or since it is at its maximum height. The other point, at time with velocity , corresponds to the moment just before the ball strikes the ground on the way back down. At this time its position is , also known as ( since it is at its maximum horizontal range. Projectile motion is symmetric about the peak, provided the object lands at the same vertical height from which is was launched, as is the case here. Hence . Part A , = -2,-5 , Extra Credit http://session.masteringphysics.com/myct/assignmentPrintView?displayM… 8 of 57 5/9/2014 8:02 PM How do the speeds , , and (at times ,

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The first sign of physiological sexual response occurs in the vagina within _____ seconds of the initiation of sexual stimulation. Question 22 options: 5-10 30-45 10-30 45-60

The first sign of physiological sexual response occurs in the vagina within _____ seconds of the initiation of sexual stimulation. Question 22 options: 5-10 30-45 10-30 45-60

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Course: PHYS 5426 — Quantum Statistical Physics Assignment #1 Instructor: Gennady Y. Chitov Date Assigned: January 15, 2014 Due Date: January 29, 2014 Problem 1. Prove [a; f(a†)] = @f(a†) @a† (1) [a†; f(a)] = −@f(a) @a (2) for arbitrary function f of operator which admits a series expansion. The Bose creation/ annihilation operators satisfy the standard commutation relations [a; a†] ≡ aa† − a†a = 1 (3) Hint: From Eqs.(1,2) one can figure out the corresponding commutation relations for the powers of creation/annihilation operators and then prove them by the method of mathematical induction. Note that for an arbitrary operator Aˆ: @A^n @A^ = nAˆn−1. Problem 2. In the presence of a constant external force acting on a one-dimensional oscillating particle its Hamiltonian becomes that of the so-called displaced oscillator, and the Schr¨odinger equation ˆH (q) = E (q) of the problem (cf. lecture notes) can be written in terms of dimensionless variables as ( − 1 2 d2 d2 + 1 2 2 − √ 2  ) () = ” () ; (4) where q = √ ~ m! and E = ~!”. a). Write the Schr¨odinger equation (4) in terms of the creation/annihilation operators of the harmonic oscillator ( = 0)  = √1 2 (a + a†) (5) d d = √1 2 (a − a†) (6) 1 Via a linear transformation to the new creation/annihilation operators ˜a†; ˜a preserving the bosonic commutation relations for ˜a†; ˜a map the problem (4) of the displaced oscillator onto that of a simple harmonic oscillator with new operators (˜a†; ˜a). b). Find the spectrum (eigenvalues) ” (E) of the displaced oscillator. c). Write the normalized eigenstates |n⟩ of the displaced Hamiltonian (4) via a† and the vacuum state |Θ◦⟩ of the new operators, i.e. ˜a|Θ◦⟩ = 0 (7) d). As follows from the completeness of the oscillator’s eigenstates, the vacuum state of the displaced oscillator |Θ◦⟩ can be related to the simple oscillator’s vacuum |0⟩ (i.e., a|0⟩ = 0) as |Θ◦⟩ = Ω(a†)|0⟩ (8) Find (up to a normalization factor) the operator function Ω(a†) relating two vacua. Hint: in working out Eqs.(7,8), employ Eqs.(1,2). Problem 3. Prove from the standard commutation relations ([ai; a † j ]∓ = ij , etc) that ⟨0|aiaja † ka † l |0⟩ = jkil ± ikjl (9) the sign depending on the statistics. Also calculate the vacuum expectation value ⟨0|ahaiaja † ka † l a† m |0⟩. Problem 4. In the formalism of second quantization the two-particle interaction term of the Hamiltonian for spinless fermions is given by ˆ V = 1 2 ∫ ∫ dxdy ˆ †(x) ˆ †(y)V(x; y) ˆ (y) ˆ (x) (10) For the short-ranged interaction V(x; y) = V(|x−y|) ≡ V(r) = e2 exp(−r)=r find ˆ V in the momentum representation. The field operators and the creation/annihilation operators in the momentum representation are related in the usual way, i.e., ˆ †(x) = ∫ dp (2)3 a†(p)e−ipx (11) Note that the limit  → 0 recovers the Coulomb (long-ranged) interaction V(r) = e2=r. What is the Fourier transform V(q) of the Coulomb interaction? 2 Problem 5. The matrix elements of a two-particle interaction from the previous problem can be written as ⟨k3k4|V|k1k2⟩ = (2)3(k1 + k2 − k3 − k4)V(q) (12) where q ≡ k3−k1 is the momentum transfer. Show that the diagonal part of the interaction operator ˆ V found on the previous problem in the k-representation, arises from momentum transfers q = 0 and q = k2−k1. Write down the two interaction terms and identify them as direct (q = 0) and exchange (q = k2 − k1) interactions. Draw the corresponding Feynman diagrams. Problem 6. Find the first correction to the temperature dependence of the chemical potential  of the degenerate ideal electron gas, assuming constant particle concentration ⟨N⟩=V . Express the result in terms of T and the zero-temperature chemical potential ◦. For the calculations the following formula (we set kB = 1) can be used: I ≡ ∫ ∞ 0 f(“)d” e(“−)=T + 1 = ∫  0 f(“)d” + 2 6 T2f′() + O(T4) (13) 3

Course: PHYS 5426 — Quantum Statistical Physics Assignment #1 Instructor: Gennady Y. Chitov Date Assigned: January 15, 2014 Due Date: January 29, 2014 Problem 1. Prove [a; f(a†)] = @f(a†) @a† (1) [a†; f(a)] = −@f(a) @a (2) for arbitrary function f of operator which admits a series expansion. The Bose creation/ annihilation operators satisfy the standard commutation relations [a; a†] ≡ aa† − a†a = 1 (3) Hint: From Eqs.(1,2) one can figure out the corresponding commutation relations for the powers of creation/annihilation operators and then prove them by the method of mathematical induction. Note that for an arbitrary operator Aˆ: @A^n @A^ = nAˆn−1. Problem 2. In the presence of a constant external force acting on a one-dimensional oscillating particle its Hamiltonian becomes that of the so-called displaced oscillator, and the Schr¨odinger equation ˆH (q) = E (q) of the problem (cf. lecture notes) can be written in terms of dimensionless variables as ( − 1 2 d2 d2 + 1 2 2 − √ 2  ) () = ” () ; (4) where q = √ ~ m! and E = ~!”. a). Write the Schr¨odinger equation (4) in terms of the creation/annihilation operators of the harmonic oscillator ( = 0)  = √1 2 (a + a†) (5) d d = √1 2 (a − a†) (6) 1 Via a linear transformation to the new creation/annihilation operators ˜a†; ˜a preserving the bosonic commutation relations for ˜a†; ˜a map the problem (4) of the displaced oscillator onto that of a simple harmonic oscillator with new operators (˜a†; ˜a). b). Find the spectrum (eigenvalues) ” (E) of the displaced oscillator. c). Write the normalized eigenstates |n⟩ of the displaced Hamiltonian (4) via a† and the vacuum state |Θ◦⟩ of the new operators, i.e. ˜a|Θ◦⟩ = 0 (7) d). As follows from the completeness of the oscillator’s eigenstates, the vacuum state of the displaced oscillator |Θ◦⟩ can be related to the simple oscillator’s vacuum |0⟩ (i.e., a|0⟩ = 0) as |Θ◦⟩ = Ω(a†)|0⟩ (8) Find (up to a normalization factor) the operator function Ω(a†) relating two vacua. Hint: in working out Eqs.(7,8), employ Eqs.(1,2). Problem 3. Prove from the standard commutation relations ([ai; a † j ]∓ = ij , etc) that ⟨0|aiaja † ka † l |0⟩ = jkil ± ikjl (9) the sign depending on the statistics. Also calculate the vacuum expectation value ⟨0|ahaiaja † ka † l a† m |0⟩. Problem 4. In the formalism of second quantization the two-particle interaction term of the Hamiltonian for spinless fermions is given by ˆ V = 1 2 ∫ ∫ dxdy ˆ †(x) ˆ †(y)V(x; y) ˆ (y) ˆ (x) (10) For the short-ranged interaction V(x; y) = V(|x−y|) ≡ V(r) = e2 exp(−r)=r find ˆ V in the momentum representation. The field operators and the creation/annihilation operators in the momentum representation are related in the usual way, i.e., ˆ †(x) = ∫ dp (2)3 a†(p)e−ipx (11) Note that the limit  → 0 recovers the Coulomb (long-ranged) interaction V(r) = e2=r. What is the Fourier transform V(q) of the Coulomb interaction? 2 Problem 5. The matrix elements of a two-particle interaction from the previous problem can be written as ⟨k3k4|V|k1k2⟩ = (2)3(k1 + k2 − k3 − k4)V(q) (12) where q ≡ k3−k1 is the momentum transfer. Show that the diagonal part of the interaction operator ˆ V found on the previous problem in the k-representation, arises from momentum transfers q = 0 and q = k2−k1. Write down the two interaction terms and identify them as direct (q = 0) and exchange (q = k2 − k1) interactions. Draw the corresponding Feynman diagrams. Problem 6. Find the first correction to the temperature dependence of the chemical potential  of the degenerate ideal electron gas, assuming constant particle concentration ⟨N⟩=V . Express the result in terms of T and the zero-temperature chemical potential ◦. For the calculations the following formula (we set kB = 1) can be used: I ≡ ∫ ∞ 0 f(“)d” e(“−)=T + 1 = ∫  0 f(“)d” + 2 6 T2f′() + O(T4) (13) 3

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Assignment 1: Coulomb’s Law Due: 8:00am on Wednesday, January 11, 2012 Note: To understand how points are awarded, read your instructor’s Grading Policy. [Switch to Standard Assignment View] Coulomb’s Law Tutorial Learning Goal: To understand how to calculate forces between charged particles, particularly the dependence on the sign of the charges and the distance between them. Coulomb’s law describes the force that two charged particles exert on each other (by Newton’s third law, those two forces must be equal and opposite). The force exerted by particle 2 (with charge ) on particle 1 (with charge ) is proportional to the charge of each particle and inversely proportional to the square of the distance between them: , where and is the unit vector pointing from particle 2 to particle 1. The force vector will be parallel or antiparallel to the direction of , parallel if the product and antiparallel if ; the force is attractive if the charges are of opposite sign and repulsive if the charges are of the same sign. Part A Consider two positively charged particles, one of charge (particle 0) fixed at the origin, and another of charge (particle 1) fixed on the y-axis at . What is the net force on particle 0 due to particle 1? Express your answer (a vector) using any or all of , , , , , , and . ANSWER: = Correct Part B Now add a third, negatively charged, particle, whose charge is (particle 2). Particle 2 fixed on the y-axis at position . What is the new net force on particle 0, from particle 1 and particle 2? Express your answer (a vector) using any or all of , , , , , , , , and . ANSWER: = Correct Part C Particle 0 experiences a repulsion from particle 1 and an attraction toward particle 2. For certain values of and , the repulsion and attraction should balance each other, resulting in no net force. For what ratio is there no net force on particle 0? Express your answer in terms of any or all of the following variables: , , , . ANSWER: = Correct Part D Now add a fourth charged particle, particle 3, with positive charge , fixed in the yz-plane at . What is the net force on particle 0 due solely to this charge? Hint D.1 Find the magnitude of force from particle 3 Hint not displayed Hint D.2 Vector components Hint not displayed Express your answer (a vector) using , , , , , , and . Include only the force caused by particle 3. ANSWER: = Correct Exercise 21.4 You have a pure (24-karat) gold ring with mass . Gold has an atomic mass of and an atomic number of . Part A How many protons are in the ring? ANSWER: = 4.27×1024 Correct Part B What is their total positive charge? ANSWER: = 6.83×105 Correct Part C If the ring carries no net charge, how many electrons are in it? ANSWER: = 4.27×1024 Correct Exercise 21.22 Two point charges are placed on the x-axis as follows: charge = 4.05 is located at 0.197 , and charge = 5.00 is at -0.296 . Part A What is the magnitude of the total force exerted by these two charges on a negative point charge = -6.00 that is placed at the origin? ANSWER: = 2.55×10−6 Correct Part B What is the direction of the total force exerted by these two charges on a negative point charge = -6.00 that is placed at the origin? ANSWER: to the + direction to the – direction perpendicular to the -axis the force is zero Correct Problem 21.66 A charge 4.97 is placed at the origin of an xy-coordinate system, and a charge -1.99 is placed on the positive x-axis at = 3.98 . A third particle, of charge 6.05 is now placed at the point = 3.98 , = 3.01 . Part A Find the x-component of the total force exerted on the third charge by the other two. ANSWER: = 8.66×10−5 Correct Part B Find the y-component of the total force exerted on the third charge by the other two. ANSWER: = −5.40×10−5 Correct Part C Find the magnitude of the total force acting on the third charge. ANSWER: = 1.02×10−4 Correct Part D Find the direction of the total force acting on the third charge. ANSWER: = -0.557 Correct between and +x-axis Problem 21.68 Two identical spheres with mass are hung from silk threads of length , as shown in the figure . Each sphere has the same charge, so . The radius of each sphere is very small compared to the distance between the spheres, so they may be treated as point charges. Part A Suppose that the angle is small, and find the equilibrium separation between the spheres (Hint: If is small, then .) Express your answer in terms of the variables , , and appropriate constants. ANSWER: = Correct

Assignment 1: Coulomb’s Law Due: 8:00am on Wednesday, January 11, 2012 Note: To understand how points are awarded, read your instructor’s Grading Policy. [Switch to Standard Assignment View] Coulomb’s Law Tutorial Learning Goal: To understand how to calculate forces between charged particles, particularly the dependence on the sign of the charges and the distance between them. Coulomb’s law describes the force that two charged particles exert on each other (by Newton’s third law, those two forces must be equal and opposite). The force exerted by particle 2 (with charge ) on particle 1 (with charge ) is proportional to the charge of each particle and inversely proportional to the square of the distance between them: , where and is the unit vector pointing from particle 2 to particle 1. The force vector will be parallel or antiparallel to the direction of , parallel if the product and antiparallel if ; the force is attractive if the charges are of opposite sign and repulsive if the charges are of the same sign. Part A Consider two positively charged particles, one of charge (particle 0) fixed at the origin, and another of charge (particle 1) fixed on the y-axis at . What is the net force on particle 0 due to particle 1? Express your answer (a vector) using any or all of , , , , , , and . ANSWER: = Correct Part B Now add a third, negatively charged, particle, whose charge is (particle 2). Particle 2 fixed on the y-axis at position . What is the new net force on particle 0, from particle 1 and particle 2? Express your answer (a vector) using any or all of , , , , , , , , and . ANSWER: = Correct Part C Particle 0 experiences a repulsion from particle 1 and an attraction toward particle 2. For certain values of and , the repulsion and attraction should balance each other, resulting in no net force. For what ratio is there no net force on particle 0? Express your answer in terms of any or all of the following variables: , , , . ANSWER: = Correct Part D Now add a fourth charged particle, particle 3, with positive charge , fixed in the yz-plane at . What is the net force on particle 0 due solely to this charge? Hint D.1 Find the magnitude of force from particle 3 Hint not displayed Hint D.2 Vector components Hint not displayed Express your answer (a vector) using , , , , , , and . Include only the force caused by particle 3. ANSWER: = Correct Exercise 21.4 You have a pure (24-karat) gold ring with mass . Gold has an atomic mass of and an atomic number of . Part A How many protons are in the ring? ANSWER: = 4.27×1024 Correct Part B What is their total positive charge? ANSWER: = 6.83×105 Correct Part C If the ring carries no net charge, how many electrons are in it? ANSWER: = 4.27×1024 Correct Exercise 21.22 Two point charges are placed on the x-axis as follows: charge = 4.05 is located at 0.197 , and charge = 5.00 is at -0.296 . Part A What is the magnitude of the total force exerted by these two charges on a negative point charge = -6.00 that is placed at the origin? ANSWER: = 2.55×10−6 Correct Part B What is the direction of the total force exerted by these two charges on a negative point charge = -6.00 that is placed at the origin? ANSWER: to the + direction to the – direction perpendicular to the -axis the force is zero Correct Problem 21.66 A charge 4.97 is placed at the origin of an xy-coordinate system, and a charge -1.99 is placed on the positive x-axis at = 3.98 . A third particle, of charge 6.05 is now placed at the point = 3.98 , = 3.01 . Part A Find the x-component of the total force exerted on the third charge by the other two. ANSWER: = 8.66×10−5 Correct Part B Find the y-component of the total force exerted on the third charge by the other two. ANSWER: = −5.40×10−5 Correct Part C Find the magnitude of the total force acting on the third charge. ANSWER: = 1.02×10−4 Correct Part D Find the direction of the total force acting on the third charge. ANSWER: = -0.557 Correct between and +x-axis Problem 21.68 Two identical spheres with mass are hung from silk threads of length , as shown in the figure . Each sphere has the same charge, so . The radius of each sphere is very small compared to the distance between the spheres, so they may be treated as point charges. Part A Suppose that the angle is small, and find the equilibrium separation between the spheres (Hint: If is small, then .) Express your answer in terms of the variables , , and appropriate constants. ANSWER: = Correct

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HIST 303 Rebels and Renegades Comparative Paper – Conroy & Drakulic In a well-written analysis of about 3 pages, compare and contrast Conroy’s Belfast Diary or Drakulic’s How We Survived Communism and Even Laughed in response to the following question: It can be argued that in the midst of deprivation and hardship, people still exercise considerable agency—or the power to act within one’s particular socio-political context. In fact, living the ordinary can be considered an act of rebellion against an imposing power. That is, people use and experience their lives as resistance to oppression or war. This is sometimes referred to as the “politics of everyday life”. How does this concept of agency play out in these works? In your response, do not simply list examples, but analyze the examples by the authors in relation to the larger themes of the course. A successful assignment will (this is a checklist, so heed it well!!!): * have a solid introduction with an arguable thesis; * be well organized with coherent paragraphs relevant to the thesis; * have a concluding paragraph that concisely and accurately summarizes the paper; * adequately analyze the histories and their connections to each other; * use relevant evidence to substantiate claims; * be analytic, not descriptive; * properly cite and punctuate quotations and evidence; * be paginated; * have an interesting title relevant to the argument (e.g. “Comparative Paper” is unacceptable); * be well written, well edited and well documented. Author Specific Points that discuss everyday activities as resistance Relate to your other Reading (Williams, Hall, Hebdige, etc.) Conroy Drakulic Working Thesis: _____________________________________________________________________ ____________________________________________________________________________________ ****FORMATTING DIRECTIONS: This paper should be 3 – 4 pages (no more), typed, doublespaced, with one-inch margins and 12-point font. This assignment is worth 25% of your grade in this course. You must head your paper with your name and date and include your name and pages (x of x) in a header or footer of each page. At the end of your paper, you must skip four lines then sign with the following: “I attest that the work contained in this document is entirely my own and it numbers x pages.” *****

HIST 303 Rebels and Renegades Comparative Paper – Conroy & Drakulic In a well-written analysis of about 3 pages, compare and contrast Conroy’s Belfast Diary or Drakulic’s How We Survived Communism and Even Laughed in response to the following question: It can be argued that in the midst of deprivation and hardship, people still exercise considerable agency—or the power to act within one’s particular socio-political context. In fact, living the ordinary can be considered an act of rebellion against an imposing power. That is, people use and experience their lives as resistance to oppression or war. This is sometimes referred to as the “politics of everyday life”. How does this concept of agency play out in these works? In your response, do not simply list examples, but analyze the examples by the authors in relation to the larger themes of the course. A successful assignment will (this is a checklist, so heed it well!!!): * have a solid introduction with an arguable thesis; * be well organized with coherent paragraphs relevant to the thesis; * have a concluding paragraph that concisely and accurately summarizes the paper; * adequately analyze the histories and their connections to each other; * use relevant evidence to substantiate claims; * be analytic, not descriptive; * properly cite and punctuate quotations and evidence; * be paginated; * have an interesting title relevant to the argument (e.g. “Comparative Paper” is unacceptable); * be well written, well edited and well documented. Author Specific Points that discuss everyday activities as resistance Relate to your other Reading (Williams, Hall, Hebdige, etc.) Conroy Drakulic Working Thesis: _____________________________________________________________________ ____________________________________________________________________________________ ****FORMATTING DIRECTIONS: This paper should be 3 – 4 pages (no more), typed, doublespaced, with one-inch margins and 12-point font. This assignment is worth 25% of your grade in this course. You must head your paper with your name and date and include your name and pages (x of x) in a header or footer of each page. At the end of your paper, you must skip four lines then sign with the following: “I attest that the work contained in this document is entirely my own and it numbers x pages.” *****

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CHM114: Exam #1 CHM 114, S2015 Exam #1, Version B Instructor: O. Graudejus Points: 100 Print Name Sign Name Student I.D. # 1. You are responsible for the information on this page. Please read it carefully. 2. If you enter your ASU ID incorrectly on the scantron, a 3 point penalty will be assessed. 3. Code your name and 10 digit affiliate identification number on the separate scantron answer sheet. Use only a #2 pencil 4. Do all calculations on the exam pages. Do not make any unnecessary marks on the answer sheet. 5. This exam consists of 25 multiple choice questions worth 4 points each and a periodic table. Make sure you have them all. 6. Choose the best answer to each of the questions and answer it on the computer-graded answer sheet. Read all responses before making a selection. 7. Read the directions carefully for each problem. 8. Avoid even casual glances at other students’ exams. 9. Stop writing and hand in your scantron answer sheet and your test promptly when instructed. LATE EXAMS MAY HAVE POINTS DEDUCTED. 10. You will have 50 minutes to complete the exam. 11. If you leave early, please do so quietly. 12. Work the easiest problems first. 13. A periodic table is attached as the last page to this exam. 14. Answers will be posted online this afternoon. Potentially useful information: K = ºC + 273.15 Avogadro’s Number = 6.022 × 1023 particles/mole 1amu = 1.66·10-24 g 1 cal=4.184 J \ -2- CHM 114: Exam #1 1) What volume (mL) of a concentrated solution of sodium hydroxide (6.00 M) must be diluted to 200.0 mL to make a 0.880 M solution of sodium hydroxide? A) 2.64 B) 176 C) 29.3 D) 26.4 E) 50.0 2) Sulfur and fluorine react in a combination reaction to produce sulfur hexafluoride: S (s) + 3 F2 (g)  SF6 (g) The maximum amount of SF6 that can be produced from the reaction of 3.5 g of sulfur with 4.5 g of fluorine is __________ g. A) 5.8 B) 3.2 C) 12 D) 16 E) 8.0 3) Of the reactions below, only __________ is not spontaneous. A) 2 2 Mg (s) 2HCl + (aq)®MgCl (aq) + H (g) B) 2 4 2 4 2 2Ni (s) + H SO (aq) ®Ni SO (aq) + H (g) C) 3 2 2Al (s) + 6HBr (aq)®2AlBr (aq) + 3H (g) D) 3 3 2 2Ag (s) + 2HNO (aq) ®2AgNO (aq) + H (g) E) 2 2 Zn (s) + 2HI (aq) ®ZnI (aq) + H (g) 4) Which solution has the same number of moles of NaOH as 40.00 mL of 0.100M solution of NaOH? A) 20.00 mL of 0.200M solution of NaOH B) 25.00 mL of 0.175M solution of NaOH C) 30.00 mL of 0.145M solution of NaOH D) 50.00 mL of 0.125M solution of NaOH E) 100.00 mL of 0.0500M solution of NaOH 5) What is the concentration (M) of a NaCl solution prepared by dissolving 9.3 g of NaCl in sufficient water to give 450 mL of solution? A) 0.35 B) 0.16 C) 0.45 D) 27 E) -2 2.7×10 -3- CHM 114: Exam #1 6) In which reaction does the oxidation number of hydrogen change? A) 2 HCl (aq) NaOH (+ aq)® NaCl (aq) + H O (l) B) 2 2 CaO (s) + H O (l) ®Ca(OH) (s) C) 4 3 4 2 2 2 2 HClO (aq) + CaCO (s) ® Ca(ClO ) (aq) + H O (l) +CO (g) D) 2 2 2 3 SO (g) + H O (l)®H SO (aq) E) 2 2 2 Na (s) + 2H O (l) ® 2 NaOH (aq) + H (g) 7) Which atom has the smallest number of neutrons? A) phosphorus-30 B) chlorine-37 C) potassium-39 D) argon-40 E) calcium-40 8) The change in the internal energy of a system that absorbs 2,500 J of heat and that has received 7,655 J of work by the surroundings is __________ J. A) -10,155 B) -5,155 C) 7 −1.91×10 D) 10,155 E) 5,155 9) When a metal and a nonmetal react, the __________ tends to lose electrons and the __________ tends to gain electrons. A) metal, metal B) nonmetal, nonmetal C) metal, nonmetal D) nonmetal, metal E) None of the above, these elements share electrons. 10) What is the oxidation number of nitrogen in HNO2? A) -5 B) -3 C) 0 D) +3 E) +5 -4- CHM 114: Exam #1 11) Elements in Group 7A are known as the __________. A) chalcogens B) alkaline earth metals C) alkali metals D) halogens E) noble gases 12) The concentration of iodide ions in a 0.193 M solution of sodium iodide is __________. A) 0.193 M B) 0.386 M C) 0.0965 M D) 0.579 M E) 0.0643 M 13) Lithium and nitrogen react to produce lithium nitride: 6Li (s) + N2 (g)  2Li3N (s) How many moles of N2 are needed to react with 1.422 mol of lithium? A) 4.26 B) 0.710 C) 0.237 D) 2.13 E) 0.118 14) The balanced equation for the decomposition of sodium azide is __________. A) 2NaN3 (s)  Na2 (s) + 3 N2 (g) B) NaN3 (s)  Na (s) + N2 (g) C) 2NaN3 (s)  2Na (s) + 3 N2 (g) D) NaN3 (s)  Na (s) + N2 (g) + N (g) E) 2NaN3 (s)  2Na (s) + 2 N2 (g) 15) A sample of CH2F2 with a mass of 9.5 g contains __________ atoms of F. A) 2.2 × 1023 B) 38 C) 3.3 × 1024 D) 4.4 × 1023 E) 9.5 -5- CHM 114: Exam #1 16) An unknown element is found to have three naturally occurring isotopes with atomic masses of 35.9675 (0.337%), 37.9627 (0.063%), and 39.9624 (99.600%). Which of the following is the unknown element? A) Ar B) K C) Cl D) Ca E) None of the above could be the unknown element. 17) The value of DH° for the reaction below is -482 kJ. Calculate the heat (kJ) released to the surroundings when 24.0 g of CO (g) reacts completely. 2 2 2CO(g) +O (g)®2CO (g) A) 3 2.89×10 B) 207 C) 103 D) 65.7 E) -482 18) Lead (II) carbonate decomposes to give lead (II) oxide and carbon dioxide: PbCO3 (s)  PbO (s) + CO2 (g) __________ grams of carbondioxide will be produced by the decomposition of 7.50 g of lead (II) carbonate? A) 1.23 B) 2.50 C) 0.00936 D) 6.26 E) 7.83 19) Combining aqueous solutions of BaCl2 and K2SO4 affords a precipitate of 4 BaSO . Which ion(s) is/are spectator ions in the reaction? A) 2 Ba only + B) K+ only C) 2 2 Ba and SO4 + − D) SO4 2- and Cl- E) K+ and Cl- 20) Which combination will produce a precipitate? A) Pb(NO3)2 (aq) and HCl (aq) B) Cu(NO3)2 (aq) and KCl (aq) C) KOH (aq) and HNO3 (aq) D) AgNO3 (aq) and HNO3 (aq) E) NaOH (aq) and Sr(NO3)2 (aq) -6- CHM 114: Exam #1 21) There are __________ sulfur atoms in 50 molecules of C4H4S2. A) 1.5 × 1025 B) 100 C) 3.0 × 1025 D) 50 E) 6.02 × 1023 22) A compound contains 38.7% K, 13.9% N, and 47.4% O by mass. What is the empirical formula of the compound? A) K2N2O3 B) KNO2 C) KNO3 D) K2NO3 E) K4NO5 23) Predict the empirical formula of the ionic compound that forms from sodium and fluorine. A) 2 Na F B) 2 NaF C) 2 3 Na F D) NaF E) 3 2 Na F 24) The mass % of Krypton in the binary compound KrF2 is __________. A) 18.48 B) 45.38 C) 68.80 D) 81.52 E) 31.20 25) The correct name for K2SO3 is __________. A) potassium sulfate B) potassium disulfide C) potassium sulfite D) potassium sulfide E) dipotassium sulfate -7- CHM 114: Exam #1

CHM114: Exam #1 CHM 114, S2015 Exam #1, Version B Instructor: O. Graudejus Points: 100 Print Name Sign Name Student I.D. # 1. You are responsible for the information on this page. Please read it carefully. 2. If you enter your ASU ID incorrectly on the scantron, a 3 point penalty will be assessed. 3. Code your name and 10 digit affiliate identification number on the separate scantron answer sheet. Use only a #2 pencil 4. Do all calculations on the exam pages. Do not make any unnecessary marks on the answer sheet. 5. This exam consists of 25 multiple choice questions worth 4 points each and a periodic table. Make sure you have them all. 6. Choose the best answer to each of the questions and answer it on the computer-graded answer sheet. Read all responses before making a selection. 7. Read the directions carefully for each problem. 8. Avoid even casual glances at other students’ exams. 9. Stop writing and hand in your scantron answer sheet and your test promptly when instructed. LATE EXAMS MAY HAVE POINTS DEDUCTED. 10. You will have 50 minutes to complete the exam. 11. If you leave early, please do so quietly. 12. Work the easiest problems first. 13. A periodic table is attached as the last page to this exam. 14. Answers will be posted online this afternoon. Potentially useful information: K = ºC + 273.15 Avogadro’s Number = 6.022 × 1023 particles/mole 1amu = 1.66·10-24 g 1 cal=4.184 J \ -2- CHM 114: Exam #1 1) What volume (mL) of a concentrated solution of sodium hydroxide (6.00 M) must be diluted to 200.0 mL to make a 0.880 M solution of sodium hydroxide? A) 2.64 B) 176 C) 29.3 D) 26.4 E) 50.0 2) Sulfur and fluorine react in a combination reaction to produce sulfur hexafluoride: S (s) + 3 F2 (g)  SF6 (g) The maximum amount of SF6 that can be produced from the reaction of 3.5 g of sulfur with 4.5 g of fluorine is __________ g. A) 5.8 B) 3.2 C) 12 D) 16 E) 8.0 3) Of the reactions below, only __________ is not spontaneous. A) 2 2 Mg (s) 2HCl + (aq)®MgCl (aq) + H (g) B) 2 4 2 4 2 2Ni (s) + H SO (aq) ®Ni SO (aq) + H (g) C) 3 2 2Al (s) + 6HBr (aq)®2AlBr (aq) + 3H (g) D) 3 3 2 2Ag (s) + 2HNO (aq) ®2AgNO (aq) + H (g) E) 2 2 Zn (s) + 2HI (aq) ®ZnI (aq) + H (g) 4) Which solution has the same number of moles of NaOH as 40.00 mL of 0.100M solution of NaOH? A) 20.00 mL of 0.200M solution of NaOH B) 25.00 mL of 0.175M solution of NaOH C) 30.00 mL of 0.145M solution of NaOH D) 50.00 mL of 0.125M solution of NaOH E) 100.00 mL of 0.0500M solution of NaOH 5) What is the concentration (M) of a NaCl solution prepared by dissolving 9.3 g of NaCl in sufficient water to give 450 mL of solution? A) 0.35 B) 0.16 C) 0.45 D) 27 E) -2 2.7×10 -3- CHM 114: Exam #1 6) In which reaction does the oxidation number of hydrogen change? A) 2 HCl (aq) NaOH (+ aq)® NaCl (aq) + H O (l) B) 2 2 CaO (s) + H O (l) ®Ca(OH) (s) C) 4 3 4 2 2 2 2 HClO (aq) + CaCO (s) ® Ca(ClO ) (aq) + H O (l) +CO (g) D) 2 2 2 3 SO (g) + H O (l)®H SO (aq) E) 2 2 2 Na (s) + 2H O (l) ® 2 NaOH (aq) + H (g) 7) Which atom has the smallest number of neutrons? A) phosphorus-30 B) chlorine-37 C) potassium-39 D) argon-40 E) calcium-40 8) The change in the internal energy of a system that absorbs 2,500 J of heat and that has received 7,655 J of work by the surroundings is __________ J. A) -10,155 B) -5,155 C) 7 −1.91×10 D) 10,155 E) 5,155 9) When a metal and a nonmetal react, the __________ tends to lose electrons and the __________ tends to gain electrons. A) metal, metal B) nonmetal, nonmetal C) metal, nonmetal D) nonmetal, metal E) None of the above, these elements share electrons. 10) What is the oxidation number of nitrogen in HNO2? A) -5 B) -3 C) 0 D) +3 E) +5 -4- CHM 114: Exam #1 11) Elements in Group 7A are known as the __________. A) chalcogens B) alkaline earth metals C) alkali metals D) halogens E) noble gases 12) The concentration of iodide ions in a 0.193 M solution of sodium iodide is __________. A) 0.193 M B) 0.386 M C) 0.0965 M D) 0.579 M E) 0.0643 M 13) Lithium and nitrogen react to produce lithium nitride: 6Li (s) + N2 (g)  2Li3N (s) How many moles of N2 are needed to react with 1.422 mol of lithium? A) 4.26 B) 0.710 C) 0.237 D) 2.13 E) 0.118 14) The balanced equation for the decomposition of sodium azide is __________. A) 2NaN3 (s)  Na2 (s) + 3 N2 (g) B) NaN3 (s)  Na (s) + N2 (g) C) 2NaN3 (s)  2Na (s) + 3 N2 (g) D) NaN3 (s)  Na (s) + N2 (g) + N (g) E) 2NaN3 (s)  2Na (s) + 2 N2 (g) 15) A sample of CH2F2 with a mass of 9.5 g contains __________ atoms of F. A) 2.2 × 1023 B) 38 C) 3.3 × 1024 D) 4.4 × 1023 E) 9.5 -5- CHM 114: Exam #1 16) An unknown element is found to have three naturally occurring isotopes with atomic masses of 35.9675 (0.337%), 37.9627 (0.063%), and 39.9624 (99.600%). Which of the following is the unknown element? A) Ar B) K C) Cl D) Ca E) None of the above could be the unknown element. 17) The value of DH° for the reaction below is -482 kJ. Calculate the heat (kJ) released to the surroundings when 24.0 g of CO (g) reacts completely. 2 2 2CO(g) +O (g)®2CO (g) A) 3 2.89×10 B) 207 C) 103 D) 65.7 E) -482 18) Lead (II) carbonate decomposes to give lead (II) oxide and carbon dioxide: PbCO3 (s)  PbO (s) + CO2 (g) __________ grams of carbondioxide will be produced by the decomposition of 7.50 g of lead (II) carbonate? A) 1.23 B) 2.50 C) 0.00936 D) 6.26 E) 7.83 19) Combining aqueous solutions of BaCl2 and K2SO4 affords a precipitate of 4 BaSO . Which ion(s) is/are spectator ions in the reaction? A) 2 Ba only + B) K+ only C) 2 2 Ba and SO4 + − D) SO4 2- and Cl- E) K+ and Cl- 20) Which combination will produce a precipitate? A) Pb(NO3)2 (aq) and HCl (aq) B) Cu(NO3)2 (aq) and KCl (aq) C) KOH (aq) and HNO3 (aq) D) AgNO3 (aq) and HNO3 (aq) E) NaOH (aq) and Sr(NO3)2 (aq) -6- CHM 114: Exam #1 21) There are __________ sulfur atoms in 50 molecules of C4H4S2. A) 1.5 × 1025 B) 100 C) 3.0 × 1025 D) 50 E) 6.02 × 1023 22) A compound contains 38.7% K, 13.9% N, and 47.4% O by mass. What is the empirical formula of the compound? A) K2N2O3 B) KNO2 C) KNO3 D) K2NO3 E) K4NO5 23) Predict the empirical formula of the ionic compound that forms from sodium and fluorine. A) 2 Na F B) 2 NaF C) 2 3 Na F D) NaF E) 3 2 Na F 24) The mass % of Krypton in the binary compound KrF2 is __________. A) 18.48 B) 45.38 C) 68.80 D) 81.52 E) 31.20 25) The correct name for K2SO3 is __________. A) potassium sulfate B) potassium disulfide C) potassium sulfite D) potassium sulfide E) dipotassium sulfate -7- CHM 114: Exam #1